openai/openai-openapi. Seeing as the LLM world has semi-standardized on imitating OpenAI's API format for a whole host of different tools, it's useful to note that OpenAI themselves maintain a dedicated repository for a OpenAPI YAML representation of their current API.
The openapi.yaml file itself is over 26,000 lines long, defining 76 API endpoints ("paths" in OpenAPI terminology) and 284 "schemas" for JSON that can be sent to and from those endpoints. A much more interesting view onto it is the commit history for that file, showing details of when each different API feature was released.
Browsing 26,000 lines of YAML isn't pleasant, so I got Claude to build me a rudimentary YAML expand/hide exploration tool. Here's that tool running against the OpenAI schema, loaded directly from GitHub via a CORS-enabled fetch() call: https://tools.simonwillison.net/yaml-explorer#.eyJ1c... - the code after that fragment is a base64-encoded JSON for the current state of the tool (mostly Claude's idea).
Update: It turns out the petstore.swagger.io demo has an (as far as I can tell) undocumented ?url= parameter which can load external YAML files, so here's openai-openapi/openapi.yaml is an OpenAPI explorer interface.